InChI key
RAOZVFGTRXLBTA-UHFFFAOYSA-N
InChI
1S/C5H10ClO2P/c1-5(2)3-7-9(6)8-4-5/h3-4H2,1-2H3
SMILES string
CC1(C)COP(Cl)OC1
assay
96%
refractive index
n20/D 1.476 (lit.)
bp
46-47 °C/1.6 mmHg (lit.)
density
1.215 g/mL at 25 °C (lit.)
Application
2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane may be used to synthesize:
- 3,5-di-O-benzyl-2-deoxy-4-O-(5,5-dimethyl-1,3,2-dioxaphosphorin-2-yl)-D-erythro-pentose diethyl dithioacetal
- (2-chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane) tetracarbonyliron, (2-Cl-DMP)Fe(CO)4
- bis(p-5,5-dimethyl-1,3,2-dioxaphosphorinano)-diiron hexacarbonyl, [(p-DMP)Fe(CO)3]2
- tungsten (Z)-1,2-diphosphite-alkene tetracarbonyl complexes
- tungsten (E)-vinyl-phosphite pentacarbonyl complexes
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
180.0 °F - closed cup
flash_point_c
82.2 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Bis(?-5, 5-dimethyl-1, 3, 2-dioxaphosphorinano)-diiron hexacarbonyl: a fluxional molecule exhibiting two types of proton site exchange.
Bartish, Charles M., and Charles S. Kraihanzel.
Inorganic Chemistry, 17(3), 735-738 (1978)
An improved synthesis of benzyl 3, 5-di-O-benzyl-2-deoxy-1, 4-dithio-d-erythro-pentofuranoside, an intermediate in the synthesis of 4'-thionucleosides.
Dyson MR, et al.
Carbohydrate Research, 216, 237-248 (1992)
Tungsten (Z)-1, 2-diphosphite-alkene and (E)-vinyl-phosphite complexes from phosphite Fischer carbene complexes.
Barluenga J, et al.
Organometallics, 16(17), 3732-3734 (1997)
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