Merck
CN

660159

Sigma-Aldrich

NaK 硅胶 (Na2K) 阶段 I

extent of labeling: ~35 wt. % Na-K loading

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别名:
Na2K-SG-I, 硅胶负载钠钾合金 (Na2K)
CAS号:
MDL编号:
PubChem化学物质编号:

蒸汽压

0 mmHg ( 20 °C)

形式

solid

自燃温度

248-257 °F

reaction suitability

reagent type: reductant

标记范围

~35 wt. % Na-K loading

密度

0.87 g/mL at 25 °C

InChI

1S/K.Na

InChI key

BITYAPCSNKJESK-UHFFFAOYSA-N

应用

Alternative to other reagents for desulfurizations, dehalogenations(as Wurtz coupling reactions), and Birch reductions.

Additionally can be used as:
  • A reducing agent for aliphatic ester substrates
  • A deprotectant in place of the typical heavy metal deprotectant

法规信息

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

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  4. What is the Department of Transportation shipping information for this product?

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  5. What is the difference between the NaK Silica gels (Na2K) , for example Stage I or Stage II?

    These alkali silica gels, which are offered by Sigma-Aldrich for SiGNa Chemistry, can reduce some of the handling precautions traditionally associated with alkali metals, while still retaining the reducing power of the parent alkali.They are classified into three categories. Stage 0 powders, like 660140 or 660159, are air-sensitive, but can easily be used in continuous-flow applications. Stage I powders, like 660167, are non-pyrophoric and dry air-stable; they can be stored for months without any change in reducing capacity. Stage II powders are easily handled in an open ambient environment, but readily react with water to produce stoichiometric yields of pure hydrogen gas. Stage II powders function well as a hydrogen source or drying agent.

  6. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

P. F. Vogt and B. Bodnar,
Spec. Chem., 29, 22-24 (2009)
Dye, J. L. et al
Journal of the American Chemical Society, 127, 9339-9339 (2005)
P. Nandi, et al.,
Tetrahedron Letters, 50, 3864-3866 (2009)

商品

SiGNa Chemistry has recently developed a technology for encapsulating alkali metals into nano-structured porous oxides to create stable, free flowing powders with varying reactivities (based on the intended application).

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