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666025

13,6-N-亚磺酰基乙酰氨基并五苯

Name: 13,6-<I>N</I>-亚磺酰基乙酰氨基并五苯
Brand: ALDRICH

97%

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别名:

16-乙酰基-6,13-二氢-15-氧化物-13,6-(环硫亚氨基)并五苯, NSFAAP, 可溶性并五苯前体

经验公式（希尔记法）:

C₂₄H₁₇NO₂S

CAS号:

454675-76-4

分子量:

383.46

MDL编号:

MFCD08457646

PubChem化学物质编号:

24884196

NACRES:

NA.23

检测方案

97%

形式

solid

mp

169-190 °C

溶解性

THF: soluble
dioxane: soluble
methylene chloride: soluble

荧光

λ_ex 251 nm; λ_em 498 nm in chloroform

储存温度

−20°C

SMILES字符串

CC(=O)N1[C@@H]2c3cc4ccccc4cc3[C@@H](c5cc6ccccc6cc25)S1=O

InChI

1S/C24H17NO2S/c1-14(26)25-23-19-10-15-6-2-4-8-17(15)12-21(19)24(28(25)27)22-13-18-9-5-3-7-16(18)11-20(22)23/h2-13,23-24H,1H3/t23-,24+,28?

InChI key

HIABOOSIYBUBKB-XUEDKKMFSA-N

一般描述

13,6-N-Sulfinylacetamidopentacene (NSFAAP) is a highly soluble pentacene precursor that can be synthesized by Lewis acid-catalyzed Diels-Alder reaction of pentacene and N-sulfinylacetamide. It can be spin coated to form an organic thin film which can be used in organic electronics.

应用

NSFAAP can be used as a conjugating polymer that can be used in designing of thin film transistors with field mobility of 0.27 cm²V^-1s^-1 and a threshold voltage parameter of -4.25 V.

制备说明

干燥薄膜在 150-200°C 时可转化为并五苯

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves

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Saudari, S. R.; Frail, P. R.; Kagan, C. R.

Applied Physics Letters, 95, 023301-023301 (2009)

An organic thin film transistor based non-volatile memory with zinc oxide nanoparticles

Lee WK, et al.

Thin Solid Films, 519(15), 5208-5211 (2011)

On-Demand Patterning of Nanostructured Pentacene Transistors by Scanning Thermal Lithography

Shaw JE

Advanced Materials, 25(4), 552-558 (2013)

High-performance, solution-processed organic thin film transistors from a novel pentacene precursor

Afzali A, et al.

Journal of the American Chemical Society, 124(30), 8812-8813 (2002)

A photopatternable pentacene precursor for use in organic thin-film transistors.

Kevin P Weidkamp et al.

Journal of the American Chemical Society, 126(40), 12740-12741 (2004-10-08)

We demonstrate that modifying pentacene to incorporate an acid-labile moiety into its molecular structure leads to a new precursor that can be easily deposited, photopatterned, and processed via wet-chemical methods to produce organic semiconducting devices exhibiting good electrical characteristics. Acidic

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