708682
RuCl[(R,R)-TsDPEN](均三甲苯)
90%
别名:
[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1,3,5-三甲苯]-钌
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关于此项目
经验公式（希尔记法）:
C30H33ClN2O2RuS
化学文摘社编号:
分子量:
622.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
InChI
1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
SMILES string
Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
InChI key
XBNBOGZUDCYNOJ-AGEKDOICSA-M
assay
90%
form
solid
mp
241-249 °C
functional group
amine, phenyl
storage temp.
2-8°C
Quality Level
Application
RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:
- (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
- Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
Legal Information
与 Takasago 合作销售，仅用于研究目的。WO9720789
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Stereoselective Synthesis of Substituted Tetrahydropyrans and Isochromans by Cyclization of Phenylseleno Alcohols.
Temperini A, et al.
The Journal of Organic Chemistry, 80(16), 8102-8112 (2015)
Dynamic Kinetic Resolution-Based Asymmetric Transfer Hydrogenation of 2-Benzoylmorpholinones and Its Use in Concise Stereoselective Synthesis of All Four Stereoisomers of the Antidepressant Reboxetine.
Son SM and Lee HK.
The Journal of Organic Chemistry, 78(17), 8396-8404 (2013)
商品
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
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