质量水平
方案
95%
反应适用性
reagent type: ligand
reaction type: [1,2]-Wittig Rearrangement
折射率
n20/D 1.466 (lit.)
沸点
42-43 °C/10 mmHg (lit.)
密度
1.187 g/mL at 25 °C (lit.)
官能团
ester
thiol
SMILES字符串
COC(=O)CS
InChI
1S/C3H6O2S/c1-5-3(4)2-6/h6H,2H2,1H3
InChI key
MKIJJIMOAABWGF-UHFFFAOYSA-N
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一般描述
巯基乙酸甲酯与抗肿瘤抗生素新抑癌蛋白的非蛋白成分反应形成 1:1 加合物 。它与异硫氰酸盐反应生成罗丹宁 。
应用
巯基乙酸甲酯用于制备：
光氧化还原催化下C–H键有机催化活化的一般策略：苄基醚的直接芳基化
产品适配我们的光反应器系列：包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
- 3-甲氧羰基-4-氧四氢硫代吡喃, 2-和4-甲氧羰基-3-氧四氢噻吩
- 巯基乙酸甲酯和氨基乙硫醇修饰的金纳米棒。
光氧化还原催化下C–H键有机催化活化的一般策略：苄基醚的直接芳基化
产品适配我们的光反应器系列：包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
132.8 °F - closed cup
闪点(°C)
56 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
An improved procedure for the preparation of 3-carbometfaoxy-4-oxotetrahydrothiopyran, 2-and 4-carbomethoxy-3-oxotetrahydrothiophene.
Liu HJ and Ngooi TK.
Canadian Journal of Chemistry, 60(4), 437-439 (1982)
T Kusakabe et al.
Biochemistry, 34(31), 9944-9950 (1995-08-08)
A double-stranded DNA cleavage mechanism by a novel enediyne type antitumor antibiotic, dynemicin A, has been investigated through sequence-dependent strand breakage of a series of duplexes containing a single nucleotide gap. We found that (1) dynemicin A breaks specifically at
Sumati Murli et al.
Applied and environmental microbiology, 71(8), 4503-4509 (2005-08-09)
Chemobiosynthesis (J. R. Jacobsen, C. R. Hutchinson, D. E. Cane, and C. Khosla, Science 277:367-369, 1997) is an important route for the production of polyketide analogues and has been used extensively for the production of analogues of 6-deoxyerythronolide B (6-dEB).
M K Vadnere et al.
Journal of medicinal chemistry, 29(9), 1714-1720 (1986-09-01)
The reaction of methyl mercaptoacetate (5) with phenyl-p-benzoquinone (6) or 5-p-benzoquinonyl-3',5'-di-O-acetyl-2'-deoxyuridine (10) resulted in the formation of the three possible adducts to the quinone rings of 6 and 10; an additional product in the reaction with 10 was the unsubstituted
W A LaMarr et al.
Proceedings of the National Academy of Sciences of the United States of America, 95(1), 102-107 (1998-02-21)
DNA superhelical tension, an important feature of genomic organization, is known to affect the interactions of intercalating molecules with DNA. However, the effect of torsional tension on nonintercalative DNA-binding chemicals has received less attention. We demonstrate here that the enediyne
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