117714
3-甲氧基苯甲酸
ReagentPlus®, 99%
别名:
间甲基水杨酸, 间茴香酸
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线性分子式:
CH3OC6H4CO2H
化学文摘社编号:
分子量:
152.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-574-9
Beilstein/REAXYS Number:
508838
MDL number:
产品名称
3-甲氧基苯甲酸, ReagentPlus®, 99%
InChI key
XHQZJYCNDZAGLW-UHFFFAOYSA-N
InChI
1S/C8H8O3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3,(H,9,10)
SMILES string
COc1cccc(c1)C(O)=O
product line
ReagentPlus®
assay
99%
bp
170-172 °C/10 mmHg (lit.)
mp
105-107 °C (lit.)
solubility
95% ethanol: soluble 50 mg/mL, clear, colorless to faintly yellow
functional group
carboxylic acid
Quality Level
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Application
3-甲氧基苯甲酸用于合成和表征铕（III）和钆（III）的 3-甲氧基苯甲酸酯。将其用于将芳族羧酸转化为甲酯并使用硼氢化钠-THF-甲醇系统还原成相应的伯醇。
General description
3-甲氧基苯甲酸是天然产物合成中的重要中间体。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Sodium borohydride reduction of aromatic carboxylic acids via methyl esters.
Saeed A and Ashraf Z.
Journal of Chemical Sciences (Bangalore), 118(5), 419-423 (2006)
Synthesis, characterization and thermal behaviour of solid-state compounds of europium (III) and gadolinium (III) 3-methoxybenzoate.
Dametto PR, et al.
Journal of Thermal Analysis and Calorimetry, 97(2), 765-768 (2009)
A S Waldman et al.
Nucleic acids research, 19(21), 5943-5947 (1991-11-11)
We determined the effect of 3-methoxybenzamide (3-MB), a competitive inhibitor of poly(ADP-ribose) polymerase (E.C. 2.4.2.30), on intrachromosomal homologous recombination in mouse Ltk- cells. We used a cell line that contained in its genome two defective Herpes thymidine kinase (tk) genes
Lloyd G Czaplewski et al.
Bioorganic & medicinal chemistry letters, 19(2), 524-527 (2008-12-10)
3-Methoxybenzamide is a weak inhibitor of the essential bacterial cell division protein FtsZ. Exploration of the structure-activity relationships of 3-methoxybenzamide analogues led to the identification of potent anti-staphylococcal compounds.
Thi-Huu Nguyen et al.
Organic letters, 7(12), 2445-2448 (2005-06-04)
[reaction: see text] If employed in THF at 0 degrees C, LTMP metalates meta-anisic acid at the doubly activated position. In contrast, n-BuLi/t-BuOK deprotonates position C-4 preferentially at low temperature. Functionalization at C-6 requires protection of the C-2 site beforehand.
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