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218251

马鞭草烯醇

Name: 马鞭草烯醇
Brand: ALDRICH

94%

别名:

(-)-4,6,6-三甲基二环[3.1.1]庚-3-烯-2-酮, 马鞭烯酮

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₄O

化学文摘社编号:

1196-01-6

分子量:

150.22

UNSPSC Code:

85151701

NACRES:

NA.22

PubChem Substance ID:

24853055

EC Number:

214-807-2

Beilstein/REAXYS Number:

1907623

MDL number:

MFCD00065445

Assay:

94%

Form:

liquid

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属性

Quality Level

100

assay

94%

form

liquid

optical activity

[α]25/D −130°, c = 10 in ethanol

refractive index

n20/D 1.496 (lit.)

bp

227-228 °C (lit.)

density

0.975 g/mL at 20 °C (lit.)

functional group

ketone

SMILES string

CC1=CC(=O)[C@H]2C[C@@H]1C2(C)C

InChI

1S/C10H14O/c1-6-4-9(11)8-5-7(6)10(8,2)3/h4,7-8H,5H2,1-3H3/t7-,8+/m0/s1

InChI key

DCSCXTJOXBUFGB-JGVFFNPUSA-N

说明

General description

(1S)-(-)-马鞭草烯酮是Suregada zanzibariensis 叶子精油的主要成分之一。它可以通过(-)-α-蒎烯的生物转化来制备。 (1S)-(-)-马鞭草烯酮对西方松甲虫（WPB）释放的聚集信息素具有对抗作用。

Application

（1S）-（−）-马鞭草烯酮可与（1R）-（+）-降蒎酮通过酸催化的电环反应，立体选择性地合成手性环型茚衍生物。它也可以作为原料用于制备具有强大抗缺血特性的含4-苯乙烯基骨架的马鞭草烯酮衍生物。

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存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

185.0 °F - closed cup

flash_point_c

85 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Constituents of the essential oil of Suregada zanzibariensis leaves are repellent to the mosquito, Anopheles gambiae ss.

Innocent E, et al.

Journal of Insect Science, 10(1), 57-57 (2010)

Discovery of novel (1S)-(-)-verbenone derivatives with anti-oxidant and anti-ischemic effects.

Chung Ju et al.

Bioorganic & medicinal chemistry letters, 23(19), 5421-5425 (2013-08-21)

A series of novel (1S)-(-)-verbenone derivatives was synthesized bearing a 4-styryl scaffold. The synthesized compounds were tested for their anti-oxidant, anti-excitotoxic, and anti-ischemic activities. These derivatives significantly reduced oxygen-glucose deprivation-induced neuronal injury and N-methyl-D-aspartic acid-evoked excitotoxicity in cortical neurons. Furthermore

Bioconversion of (+)-and (-)-alpha-pinene to (+)-and (-)-verbenone by plant cell cultures of Psychotria brachyceras and Rauvolfia sellowii.

Limberger RP, et al.

Electronic journal of Biotechnology, 10(4), 500-507 (2007)

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全球贸易项目编号

货号	GTIN
218251-10G	04061838775412
218251-50G	04061837392351