主要文件

查看所有文档

481084

rac-BINAP

Name: rac-BINAP
Brand: ALDRICH

97%

别名:

(±)-2,2′-双(二苯基膦)-1,1′-联萘, 2,2′-双(二苯基膦)-1,1′-联萘, (±)-BINAP, [1,1′-联萘]-2,2′-双二苯膦

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

线性分子式:

[(C₆H₅)₂PC₁₀H₆-]₂

化学文摘社编号:

98327-87-8

分子量:

622.67

UNSPSC Code:

12352005

PubChem Substance ID:

24871738

NACRES:

NA.22

Beilstein/REAXYS Number:

5321443

MDL number:

MFCD00010805

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

Quality Level

200

product line

Buchwald Ligand

assay

97%

reaction suitability

reaction type: Cross Couplings, reagent type: ligand
reaction type: Acylations, reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-C Bond Formation, reagent type: ligand
reaction type: Decarboxylations, reagent type: ligand
reaction type: Stille Coupling

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

283-286 °C (lit.)

functional group

phosphine

greener alternative category

Aligned

SMILES string

P(c8ccccc8)(c7ccccc7)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5ccccc5)c4ccccc4)cccc3

InChI

1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H

InChI key

MUALRAIOVNYAIW-UHFFFAOYSA-N

说明

General description

外消旋型 BINAP。

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is an outstanding chiral ligand for asymmetric hydrogenation catalysis, providing extremely high enantioselective recognition. Click here for more information.

Application

钯催化芳基胺偶联反应的配体，用于制备去甲基硫代秋水仙碱。可与 Cu(II) 联合使用催化芳基磺酰胺加成反应生成苯乙烯和烯烃。亦可用于钯催化的三联吡啶胺化反应。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

商品

AdQPhos and Pd pre catalysts for alpha arylation reaction

Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.

全球贸易项目编号

货号	GTIN
481084-25G	04061832388519
481084-100G	04061833553305
481084-500G	04061833502709
481084-5G	04061832388526