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181315

Sigma-Aldrich

Polyacrylonitrile

average Mw 150,000 (Typical)

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Synonym(s):
Vinyl cyanide
Linear Formula:
(C3H3N)n
CAS Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

mol wt

average Mw 150,000 (Typical)

refractive index

n20/D 1.514

transition temp

Tm 317 °C
Tg 85 °C

density

1.184 g/mL at 25 °C (lit.)

SMILES string

C=CC#N

InChI

1S/C3H3N/c1-2-3-4/h2H,1H2

InChI key

NLHHRLWOUZZQLW-UHFFFAOYSA-N

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General description

PAN molecule has strong polar nitrile groups.It is relatively insoluble in nature. PAN based carbon fibers possess very high strength compared to other polymeric precursors. When subjected to heat treatment, it can produce high carbon yield giving rise to thermally stable, highly oriented, graphite like molecular structure. Generating carbon-fiber from PAN based fiber is a combination of three processes-- namely stabilization, carbonization and graphitization.

Application

Polyacrylonitrile (PAN) is used as polymeric carbon precursor to form carbon fibers, electrospun activated carbon materials having meso-macro pores, carbon black additives.These are consecutively used in hydrogen storage, EMI shielding, electrochemistry, separation processes. It may find applications in PAN based single walled carbon nanotube composites.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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  4. What is Product 181315, Polyacrylonitrile, soluble in?

    Some common solvents that can be used are DMSO, N,N-dimethylformamide, ethylene carbonate, propylene carbonate, and nitromethane.

  5. What is the degradation temperature of Product 181315, Polyacrylonitrile?

    This product has excellent thermal stability below 150°C, but will degrade above this temperature.

  6. Will Product 181315, Polyacrylonitrile, contain acrylonitrile?

    The product may contain trace amounts of the monomer acrylonitrile.  We do not test for the levels of starting material still present in the final polymer.

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    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

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Ji Sun Im et al.
Journal of colloid and interface science, 318(1), 42-49 (2007-11-09)
Polyacrylonitrile (PAN)-based carbon nanofibers (CNFs) were prepared by using electrospinning method and heat treatment to get the media for hydrogen adsorption storage. Potassium hydroxide and zinc chloride activations were conducted to increase specific surface area and pore volume of CNFs.
Fluorination effects of carbon black additives for electrical properties and EMI shielding efficiency by improved dispersion and adhesion.
Im JS, et al.
Carbon, 47(11), 2640-2647 (2009)
Superior prospect of chemically activated electrospun carbon fibers for hydrogen storage
Im JS, et al.
Mat. Res. Bul., 44(9), 1871-1878 (2009)
Prevention of dialysis-related amyloidosis using the polyacrylonitrile AN69 membrane.
J Chanard
Contributions to nephrology, 112, 137-144 (1995-01-01)
The improved electrical conductivity of carbon nanofibers by fluorinated MWCNTs.
Im JS, et al.
Journal of Industrial and Engineering Chemistry (Amsterdam, Netherlands), 15(5), 699-702 (2009)

Articles

In this article, we discuss issues critical to successful application of the electrospinning technique, including control of individual nanofibers to form secondary structures and assembly of nanofibers into 3D architectures.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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