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Merck
CN

777684

Reduced graphene oxide

greener alternative

Synonym(s):

rGO

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About This Item

Linear Formula:
CxOyHz
NACRES:
NA.23
UNSPSC Code:
12352103
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description

chemically reduced

Quality Level

form

powder

composition

Carbon, ≥75 wt. % , Nitrogen, >5 wt. % , Oxygen, <22 wt. %

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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surface area

450 m2/g

conductivity

>600 S/m

solubility

water: insoluble

greener alternative category

General description

The structure of graphene oxide is similar to graphene containing residual oxygen, heteroatoms and structural defects. Reduced graphene oxide (rGO) can be extracted as thin film from an aqueous solution of graphite oxide (GO) slurry. Many modern procedures for the synthesis of GO are based on the Hummers method, in which graphite is oxidized by a solution of potassium permanganate in sulfuric acid. Reduction of GO using hydrazine has been reported. However, hydrazine is highly toxic and can potentially functionalize GO with nitrogen heteroatoms. Because of these issues, alternatives to hydrazine including NaBH4, ascorbic acid, and HI, among others have been used for the reduction of GO. GO can be reduced as a thin film or in an aqueous solution. Reduction methods have been recently reviewed.
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Application

The spin-coated reduced graphene oxide (rGO) thin films have been used as annode buffer layer to fabricate bulk heterojunction org. solar cells. PEGylated rGO may be used as:
  • chemical sensors, biosensors
  • as transparent electrodes in light emitting diodes (LEDs) and ITOs
  • in lithium ion batteries.

Preparation Note

  • Reduction method: Chemically reduced
  • Color: Black
  • Odor: Odorless
  • Solubility: Insoluble
  • Dispersability: It can be dispersed at low concentrations (<0.1mg/mL) in NPM, DMSO, DMF
  • Electrical conductivity: > 600S/m
  • BET surface area: 450 m2/g


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

Since its discovery little more than a decade ago,1 the two-dimensional (2D) allotrope of carbon—graphene—has been the subject of intense multidisciplinary research efforts.

3D printing is a type of additive manufacturing that can be used to rapidly fabricate components with highly customizable geometries.

Fluorescence quenching microscopy visualizes 2D materials like graphene and MoS2 rapidly, inexpensively, and with high fidelity.

View All Articles

Goki Eda et al.
Nature nanotechnology, 3(5), 270-274 (2008-07-26)
The integration of novel materials such as single-walled carbon nanotubes and nanowires into devices has been challenging, but developments in transfer printing and solution-based methods now allow these materials to be incorporated into large-area electronics. Similar efforts are now being
Monique C P Mendonça et al.
Nanomaterials (Basel, Switzerland), 9(6) (2019-06-15)
Graphene-based nanomaterials (GBNs) possess unique physicochemical properties, allowing a wide range of applications in physical, chemical, and biomedical fields. Although GBNs are broadly used, information about their adverse effects on ecosystem health, especially in the terrestrial environment, is limited. Therefore
Zhang; Liming;
Journal of Material Chemistry B: Materials for Biology and Medicine, 1(6), 749-755 (2013)



Global Trade Item Number

SKUGTIN
777684-250MG04061835563876
777684-500MG04061835512089