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132225

Troger′s Base

Name: Troger′s Base
Brand: ALDRICH

98%

Synonym(s):

2,8-Dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

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About This Item

Empirical Formula (Hill Notation):

C₁₇H₁₈N₂

CAS Number:

529-81-7

Molecular Weight:

250.34

NACRES:

NA.22

PubChem Substance ID:

24847554

UNSPSC Code:

12352100

MDL number:

MFCD00134397

Assay:

98%

Form:

powder

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Properties

Quality Level

100

assay

98%

form

powder

technique(s)

photometry: suitable

mp

133-136 °C (lit.)

SMILES string

Cc1ccc2[N@@H]3C[N@@H](Cc2c1)c4ccc(C)cc4C3

InChI

1S/C17H18N2/c1-12-3-5-16-14(7-12)9-18-11-19(16)10-15-8-13(2)4-6-17(15)18/h3-8H,9-11H2,1-2H3

InChI key

SXPSZIHEWFTLEQ-UHFFFAOYSA-N

Description

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Enantioseparation of tetrahydropalmatine and Tröger's base by molecularly imprinted monolith in capillary electrochromatography.

Junjie Ou et al.

Journal of biochemical and biophysical methods, 70(1), 71-76 (2006-09-19)

Two chiral compounds, Tröger's base and tetrahydropalmatine, were enantioseparated on the (5S, 11S)-(-)-Tröger's base and l-tetrahydropalmatine imprinted monolithic capillary columns with CEC, respectively. The monoliths were prepared by in situ thermal-initiated copolymerization of methacrylic acid (MAA) and ethylene dimethacrylate (EDMA).

Tröger's base-functionalised organic nanoporous polymer for heterogeneous catalysis.

Xin Du et al.

Chemical communications (Cambridge, England), 46(6), 970-972 (2010-01-29)

An organic nanoporous polymer (BET surface area of 750 m(2) g(-1)) containing bicovalently-bonded Tröger's base as functional moieties in the network was synthesized, characterised, and further applied as a promising heterogeneous catalyst in the addition reaction of diethylzinc to aromatic

The mechanism of Tröger's base formation probed by electrospray ionization mass spectrometry.

Carlos A M Abella et al.

The Journal of organic chemistry, 72(11), 4048-4054 (2007-05-03)

Using direct infusion electrospray ionization mass and tandem mass spectrometric experiments [ESI-MS(/MS)], we have performed on-line monitoring of some reactions used to form Tröger's bases. Key intermediates, either as cationic species or as protonated forms of neutral species, have been

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Global Trade Item Number

SKU	GTIN
M8278-.1MG	04061833421307
M8437-10UG	04061834063162
132225-5G	04061838728913