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Merck
CN

150193

Triphenylvinylphosphonium bromide

97%

Synonym(s):

Ethenyltriphenylphosphonium bromide, NSC 84065, Schweizer’s Reagent, Vinyltriphenylphosphonium bromide

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About This Item

Linear Formula:
CH2=CHP(Br)(C6H5)3
CAS Number:
Molecular Weight:
369.23
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
225-740-3
Beilstein/REAXYS Number:
4168860
MDL number:
Assay:
97%
Form:
powder
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reaction suitability

core: phosphonium, reaction type: C-C Bond Formation

mp

176-178 °C (lit.)

storage temp.

2-8°C

InChI key

VRAYVWUMBAJVGH-UHFFFAOYSA-M

InChI

1S/C20H18P.BrH/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h2-17H,1H2;1H/q+1;/p-1

SMILES string

[Br-].C=C[P+](c1ccccc1)(c2ccccc2)c3ccccc3

assay

97%

Quality Level

form

powder

Application

Reactant involved in:
  • Asymmetric conjugate addition and intramolecular cyclization
  • Condensation with benzoxazinediones
  • Intramolecular dehydrobromination
  • Schweizer reaction
  • Cycloaddition with nitro ketone Baylis-Hillman adducts
Reagent for the synthesis of heterocycles.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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