176494
Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]
Synonym(s):
Eu(facam)3, Eu(tfc)3, Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate], Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)
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About This Item
InChI key
BWIHMSGCCRUUCZ-NCJHBDPTSA-K
InChI
1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;
SMILES string
CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F
optical activity
[α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
technique(s)
NMR: suitable
functional group
fluoro, ketone
Quality Level
Application
- The synthesis of europium acetylcamphorate phosphine oxide complexes
- Reactions with 1,10-N,N′-phenanthroline dioxide derivatives
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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