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Merck
CN

237523

Palladium on barium carbonate

greener alternative

reduced, extent of labeling: 5 wt. % loading

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About This Item

Linear Formula:
Pd
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
24854250
NACRES:
NA.23
MDL number:
MFCD03427451

Key Documents

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SMILES string

[Pd++].[Ba++].[O-]C([O-])=O.[O-]C([O-])=O

InChI

1S/2CH2O3.Ba.Pd/c2*2-1(3)4;;/h2*(H2,2,3,4);;/q;;2*+2/p-4

InChI key

NFXIBAPFNPIUGD-UHFFFAOYSA-J

form

solid

reaction suitability

reagent type: catalyst
core: palladium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

extent of labeling

5 wt. % loading

greener alternative category

Enabling,

Quality Level

100

Related Categories

Application

Palladium on barium carbonate (5% Pd/BaCO3) is a palladium catalyst that can be used in the cross-coupling reaction of arenediazonium salts with boronic acid at low catalytic loading. It can also be used as a catalyst in the diastereoselective hydrogenations of the imine for the synthesis of chiral trifluoromethyl benzylamines.

Other Notes

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT7329
MKCQ0242
MKBS5971V
11504TR
09131KX

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Efficient and Practical Cross-Coupling of Arenediazonium Tetrafluoroborate Salts with Boronic Acids Catalyzed by Palladium (0)/Barium Carbonate
Felpin F and Fouquet E
advanced synthesis and catalysis, 350(6), 863-868 (2008)
Efficient and Practical Cross-Coupling of Arenediazonium Tetrafluoroborate Salts with Boronic Acids Catalyzed by Palladium (0)/Barium Carbonate
Felpin F and Fouquet E
Advanced Synthesis & Catalysis, 350(6), 863-868 (2008)
Synthesis of Chiral Trifluoromethyl Benzylamines by Heterogeneous Catalytic Reductive Amination
Dasgupta S, et al.
Topics in Catalysis, 59(13-14), 1207-1213 (2016)

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