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Merck
CN

262056

Dibromoborane dimethyl sulfide complex solution

1.0 M in methylene chloride

Synonym(s):

Dibromo(dimethyl sulfide)(hydro)boron solution, Dibromo(dimethyl sulfide)borane solution, Dibromoborane compound with dimethylsulfane solution, Dibromoborane dimethyl sulfide solution

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About This Item

Linear Formula:
(CH3)2S · BHBr2
CAS Number:
Molecular Weight:
233.76
UNSPSC Code:
12352112
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4449985
Form:
liquid
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InChI

1S/C2H6S.BBr2H/c1-3-2;2-1-3/h1-2H3;1H

SMILES string

CSC.BrBBr

InChI key

PGSRDLGPKTVELT-UHFFFAOYSA-N

form

liquid

reaction suitability

reagent type: reductant

concentration

1.0 M in methylene chloride

density

1.415 g/mL at 25 °C

functional group

thioether

Quality Level

Application

Reactant for:
  • Reductive elimination C-C bond forming reactions
  • Lithiation-borylation reaction with Hoppe′s lithiated carbamates
  • Preparation of boron analogues of uracil
  • Boronation reactions for formation of cyclic boronium salts
  • Hydroboration reactions
  • Ring opening of terminal epoxides

signalword

Danger

target_organs

Central nervous system

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

80.6 °F - closed cup

flash_point_c

27 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3 - Water-react. 2

Regulatory Information

危险化学品
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