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Merck
CN

268569

三甲基铝 溶液

2.0 M in hexanes

别名:

Trimethylalane

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关于此项目

线性分子式:
(CH3)3Al
化学文摘社编号:
分子量:
72.09
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587197
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form

liquid

Quality Segment

concentration

2.0 M in hexanes

density

0.683 g/mL at 25 °C

SMILES string

C[Al](C)C

InChI

1S/3CH3.Al/h3*1H3;

InChI key

JLTRXTDYQLMHGR-UHFFFAOYSA-N

General description

Trimethylaluminum is a Lewis acid having wide applications in organic synthesis. It is employed in organic reactions like cross-coupling reaction, methylenation, carboalumination, cyclopropanation, and rearrangement reactions. Tebbe Reagent (methylenation agent) can be prepared in situ by reacting trimethylaluminum with dichlorobis(cyclopentadienyl)titanium.

Application

与 4-溴-2,6-二叔丁基苯酚(货号394378)一起用于通过环氧化物的选择性重排制备各种羰基化合物。


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signalword

Danger

target_organs

Central nervous system

supp_hazards

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

flash_point_f

-0.4 °F - closed cup

flash_point_c

-18 °C - closed cup

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1



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分析证书(COA)

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