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Merck
CN

279811

Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate

98%

Synonym(s):

Cobaltocenium hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C10H10CoF6P
CAS Number:
Molecular Weight:
334.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
235-655-3
MDL number:
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InChI key

IASMSXQWVNBFOM-UHFFFAOYSA-N

InChI

1S/2C5H5.Co.F6P/c2*1-2-4-5-3-1;;1-7(2,3,4,5)6/h2*1-5H;;/q;;+1;-1

SMILES string

[Co+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

assay

98%

reaction suitability

core: cobalt, reagent type: catalyst

Quality Level

Application

Uses:
  • Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
  • Reactant for modification of organometallic electrodes surfaces through cathodic reduction
  • Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers

wgk

WGK 3

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Javiera Cáceres et al.
Physical chemistry chemical physics : PCCP, 19(3), 2574-2582 (2017-01-07)
Biosupramolecular assemblies combining cucurbit[n]urils (CB[n]s) and proteins for the targeted delivery of drugs have the potential to improve the photoactivity of photosensitizers used in the photodynamic therapy of cancer. Understanding the complexity of these systems and how it affects the

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