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Merck
CN

309206

Rhodium(III) nitrate solution

~10 % (w/w) (Rh in >5 wt. % HNO3)

Synonym(s):

Aqueous rhodium nitrate, Rhodium trinitrate, Rhodium(3+)trinitrate

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About This Item

Linear Formula:
Rh(NO3)3
Molecular Weight:
288.92
NACRES:
NA.23
PubChem Substance ID:
24858717
UNSPSC Code:
12352302
MDL number:
MFCD00011201
Form:
liquid

Key Documents

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Product Name

Rhodium(III) nitrate solution, ~10 % (w/w) (Rh in >5 wt. % HNO3)

InChI

1S/Rh

SMILES string

[Rh]

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

form

liquid

reaction suitability

core: rhodium

concentration

≥5.0% (NaOH basis (wt% HNO3, titration))
~10 % (w/w) (Rh in >5 wt. % HNO3)

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

Quality Level

100

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Related Categories

Application

  • The saga of rhodium (III) nitrate complexes and their speciation in solution: An integrated experimental and quantum chemical study of rhodium(III) nitrate complexes in solution (SN Vorobyeva et al., 2022).

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 3 - Skin Corr. 1A

supp_hazards

EUH071

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

易制爆化学品
危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCW4989
MKCV9665
MKCV1210
MKCT5687
MKCR9518

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Simone Pollastri et al.
Journal of hazardous materials, 298, 282-293 (2015-06-16)
Although asbestos represents today one of the most harmful contaminant on Earth, in 72% of the countries worldwide only amphiboles are banned while controlled use of chrysotile is allowed. Uncertainty on the potential toxicity of chrysotile is due to the
Dong Jin Lee et al.
Angewandte Chemie (International ed. in English), 54(46), 13715-13718 (2015-09-18)
A new type of intermolecular rhodium(II)-catalyzed [5+3] cycloaddition has been developed. This higher-order cycloaddition between pyridinium zwitterion 1,5-dipole equivalents and enol diazoacetates enables the formation of eight-membered heterocyclic skeletons, which are otherwise difficult to construct. The optimized cycloaddition occurs efficiently under
Pablo E Guzmán et al.
Angewandte Chemie (International ed. in English), 53(48), 13083-13087 (2014-10-01)
A regio-, diastereo-, and enantioselective [4+3] cycloaddition between vinylcarbenes and dienes has been achieved using the dirhodium tetracarboxylate catalyst [Rh2(S-BTPCP)4]. This methodology provides facile access to 1,4-cycloheptadienes that are regioisomers of those formed from the tandem cyclopropanation/Cope rearrangement reaction of
Chumin Zhao et al.
Medical physics, 42(11), 6294-6308 (2015-11-02)
Large area x-ray imagers based on complementary metal-oxide-semiconductor (CMOS) active pixel sensor (APS) technology have been proposed for various medical imaging applications including digital breast tomosynthesis (DBT). The low electronic noise (50-300 e-) of CMOS APS x-ray imagers provides a
Malene Outzen et al.
Nutrients, 7(1), 608-624 (2015-01-20)
Selenium status of the Danish population is below that assumed optimal for the suggested protective effects against chronic diseases, including certain cancers. Fish and shellfish are important dietary sources of selenium in Denmark. We investigated the effect of increased fish
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