359009
Cerium(IV) sulfate
powder
Synonym(s):
Ceric sulfate, Cerium disulfate
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About This Item
Linear Formula:
Ce(SO4)2
CAS Number:
Molecular Weight:
332.24
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Product Name
Cerium(IV) sulfate,
form
powder
Quality Level
reaction suitability
core: cerium
reagent type: catalyst
density
3.01 g/mL at 25 °C (lit.)
SMILES string
[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
InChI
1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4
InChI key
VZDYWEUILIUIDF-UHFFFAOYSA-J
Related Categories
Application
Cerium(IV) sulfate can be used to catalyze:
- Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
- Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
- Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.
Reactant for:
- Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions
- Oxidizing agent
Other Notes
may contain excess sulfate
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Cerimetric determination of catecholamines.
M I Walash et al.
Journal de pharmacie de Belgique, 39(2), 88-92 (1984-03-01)
Basharat Ali et al.
Journal of Asian natural products research, 17(8), 843-850 (2015-03-19)
Chromatographic purification of the ethyl acetate soluble fraction from the methanolic extract of Atriplex lasiantha yielded a new triterpenoid, 7β,15α,16β-trihydroxyolean-12-ene-28,30-dioic acid-3-O-β-D-xylopyranoside (1), along with two known triterpenoids, rotundifolioside I (2) and corchorusin B (3). Structures of the compounds 1-3 were
Ceric-sulfate-catalyzed synthesis of 14-aryl-or 14-alkyl-14 H-dibenzo [aj] xanthene under conventional heating and microwave irradiation.
Selvam N P, et al.
Canadian Journal of Chemistry, 85(11), 989-995 (2007)
Hidayat Hussain et al.
Journal of Asian natural products research, 17(7), 733-737 (2015-01-07)
Phytochemical investigation of the endophytic fungus Microdiplodia sp. afforded a new m-anisaldehyde derivative named microdiplanol (1) and a new 24-methylcholestanol derivative named microdiplane (2). Their structures were confirmed by a comprehensive analysis of 1D and 2D NMR and mass spectrometric
Cerium catalyzed selective oxidation of secondary alcohols in the presence of primary ones.
Tomioka H, et al.
Tetrahedron Letters, 23(5), 539-542 (1982)
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