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Merck
CN

359009

Cerium(IV) sulfate

powder

Synonym(s):

Ceric sulfate, Cerium disulfate

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About This Item

Linear Formula:
Ce(SO4)2
CAS Number:
Molecular Weight:
332.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
237-029-5
MDL number:
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Product Name

Cerium(IV) sulfate,

form

powder

Quality Level

reaction suitability

core: cerium, reagent type: catalyst

density

3.01 g/mL at 25 °C (lit.)

SMILES string

[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4

InChI key

VZDYWEUILIUIDF-UHFFFAOYSA-J

Application

Cerium(IV) sulfate can be used to catalyze:
  • Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
  • Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
  • Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.

Reactant for:
  • Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions

  • Oxidizing agent

Other Notes

may contain excess sulfate


pictograms

CorrosionEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Radamés Alvarez-Zapata et al.
Journal of chromatography. A, 1422, 213-221 (2015-10-31)
This work describes the use of Colubrina greggii as a model to investigate the use of chemometric analysis combined with data from a leishmanicidal bioassay, using Principal Component Analysis (PCA) and Orthogonal Projections to Latent Structures (O-PLS), to detect biologically
Amarinder Singh et al.
Toxicology and applied pharmacology, 318, 8-15 (2017-01-26)
The limiting factor for the use of Cisplatin in the treatment of different type of cancers is its toxicity and more specifically urogenital toxicity. Oxidative stress is a well-known phenomenon associated with Cisplatin toxicity. However, in Cisplatin treated group, abnormal
Ju Peng Wang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(1), 204-208 (2008-02-05)
A simple, sensitive and rapid flow-injection chemiluminescence method has been developed for the determination of ferulic acid based on the chemiluminescence reaction of ferulic acid with rhodamine 6G and ceric sulfate in sulphuric acid medium. Strong chemiluminescence signal was observed



Global Trade Item Number

SKUGTIN
359009-25G04061838097798
359009-100G04061838253477