417297
Methylzinc chloride solution
2.0 M in THF
Synonym(s):
Chloromethylzinc
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About This Item
Linear Formula:
CH3ZnCl
CAS Number:
Molecular Weight:
115.88
Beilstein:
969141
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
form
liquid
Quality Level
concentration
2.0 M in THF
bp
67 °C
density
1.033 g/mL at 25 °C
SMILES string
C[Zn]Cl
InChI
1S/CH3.ClH.Zn/h1H3;1H;/q;;+1/p-1
InChI key
ASUSLKVOTPUROZ-UHFFFAOYSA-M
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Application
Methylzinc chloride can be used in:
- Ni-catalyzed one-pot Negishi coupling with amino-heteroaryl chlorides.
- Cross-coupling with aryl fluorides in the presence of a nickel catalyst.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Nickel-catalyzed cross-coupling of aryl fluorides and organozinc reagents
Zhu F and Wang Z
The Journal of Organic Chemistry, 79(10), 4285-4292 (2014)
A convenient one-pot Negishi coupling of amino-heteroaryl chlorides and alkyl bromides
Walters IAS
Tetrahedron Letters, 47(3), 341-344 (2006)
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