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线性分子式:
[(CH3)2CH]2NP[OC(CH3)3]2
化学文摘社编号:
分子量:
277.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
Beilstein/REAXYS Number:
4858847
产品名称
N,N-二异丙基亚磷酰胺二叔丁基, 95%
Quality Segment
assay
95%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.444 (lit.)
bp
85-90 °C/0.2 mmHg (lit.)
density
0.879 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CC(C)N(C(C)C)P(OC(C)(C)C)OC(C)(C)C
InChI
1S/C14H32NO2P/c1-11(2)15(12(3)4)18(16-13(5,6)7)17-14(8,9)10/h11-12H,1-10H3
InChI key
YGFLCNPXEPDANQ-UHFFFAOYSA-N
Application
二叔丁基 N,N-二异丙基亚磷酰胺是引入叔丁基保护的磷酸基团的通用试剂。它通常用于生物分子的磷酸化。它还可用于合成氨基磷酸酯连接的糖缀合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
