461490
(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine
96%
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About This Item
Linear Formula:
C10H7CH(CH3)N(CH3)2
CAS Number:
Molecular Weight:
199.29
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
96%
InChI
1S/C14H17N/c1-11(15(2)3)13-10-6-8-12-7-4-5-9-14(12)13/h4-11H,1-3H3/t11-/m1/s1
SMILES string
C[C@@H](N(C)C)c1cccc2ccccc12
InChI key
AXRXYILTIWBHEP-LLVKDONJSA-N
assay
96%
optical activity
[α]23/D +43°, c = 2 in methanol
refractive index
n20/D 1.591 (lit.)
bp
218 °C (lit.)
density
1 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
Related Categories
Application
(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine can react with palladium acetate in acetic acid to form cyclopalladated naphthyl adduct.
Base for kinetic resolution of alcohols and acyl halides.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Optically active cyclopalladated compounds containing P-chiral ligands. Restricted rotation around the Pd? P bond.
Albert J, et al.
Journal of Organometallic Chemistry, 634(1), 83-89 (2001)
Weidert, P.J. et al.
Liebigs Ann. Chem., 533-533 (1989)
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