469033
Pentylmagnesium chloride solution
2.0 M in THF
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About This Item
Linear Formula:
CH3(CH2)4MgCl
CAS Number:
Molecular Weight:
130.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
Concentration:
2.0 M in THF
InChI
1S/C5H11.ClH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
SMILES string
CCCCC[Mg]Cl
InChI key
OHLJPYMGJFINNA-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in THF
bp
65 °C
density
0.967 g/mL at 25 °C
storage temp.
2-8°C
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.0 °F - closed cup
flash_point_c
-17.2 °C - closed cup
ppe
Faceshields, Gloves, Goggles
Regulatory Information
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Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method
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