497517
Benzylzinc bromide solution
0.5 M in THF
Synonym(s):
Benzylbromozinc, Benzylzinc(II) bromide, Bromo(phenylmethyl)zinc
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About This Item
Linear Formula:
C6H5CH2ZnBr
CAS Number:
Molecular Weight:
236.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Quality Level
concentration
0.5 M in THF
density
0.978 g/mL at 25 °C
functional group
phenyl
storage temp.
2-8°C
SMILES string
Br[Zn]Cc1ccccc1
InChI
1S/C7H7.BrH.Zn/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
InChI key
OQPRTUBCROVGHA-UHFFFAOYSA-M
Application
Benzylzinc bromide solution can be used as a nucleophile for the Mannich-type synthesis of 1,2-diarylethylpiperazines. It can also undergo C−C cross coupling reactions with aryl halides.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.0 °F - closed cup
flash_point_c
-17.22 °C - closed cup
Regulatory Information
危险化学品
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Straightforward three-component synthesis of diarylmethylpiperazines and 1, 2-diarylethylpiperazines.
Sengmany S, et al.
Tetrahedron, 63(18), 3672-3681 (2007)
Nickel Complexes Modified by O, N, O?-Ligands as Synthons for the Straightforward Synthesis of Highly Efficient Precatalysts for C-C Bond Formation.
Someya CI, et al.
Asian Journal of Organic Chemistry, 1(4), 322-326 (2012)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 497517-50ML | 04061832417936 |