518093
Ethyl (triphenylphosphoranylidene)pyruvate
95%
Synonym(s):
2-Ethoxycarbonyl-2-oxoethylidenetriphenylphosphorane, NSC 647346, [(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester
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About This Item
InChI
1S/C23H21O3P/c1-2-26-23(25)22(24)18-27(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,2H2,1H3
SMILES string
CCOC(=O)C(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI key
OQLOPRPWPANPIE-UHFFFAOYSA-N
assay
95%
reaction suitability
reaction type: C-C Bond Formation
mp
175 °C (dec.) (lit.)
functional group
ester, ketone, phosphine
Quality Level
Related Categories
Application
- Wittig condensation
- Chemoenzymic preparation of hexafluoroleucine and tetrafluoroleucine
Reactant for synthesis of:
- Ahiral and chiral cyclic dehydro-α-amino acid derivatives through nucleophilic addition
- Peptidyl α-keto-based inhibitors of cruzain
- Deoxyfluoro-L-arabinofuranosyl triazole nucleoside derivatives with antiviral activity
- Anti-human immunodificiency virus analogs
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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