529745
Isopropyllithium solution
0.7 M in pentane
Synonym(s):
2-Lithiopropane, 2-Propyllithium
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About This Item
Linear Formula:
(CH3)2CHLi
CAS Number:
Molecular Weight:
50.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Concentration:
0.7 M in pentane
InChI
1S/C3H7.Li/c1-3-2;/h3H,1-2H3;
SMILES string
[Li]C(C)C
InChI key
HDSLTIHESBGENB-UHFFFAOYSA-N
concentration
0.7 M in pentane
bp
35-36 °C
density
0.632 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Application
Used in a study of the alkylative ring opening of N-sulfonyl protected aziridines providing amino alcohols and ethers.
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-31.0 °F - closed cup
flash_point_c
-35 °C - closed cup
Regulatory Information
危险化学品
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David M Hodgson et al.
The Journal of organic chemistry, 71(22), 8510-8515 (2006-10-27)
Organolithium-induced alkylative ring opening of N-sulfonyl-protected aziridinyl ethers is described. The reactions were efficiently carried out with a variety of organolithiums, providing a promising new strategy to unsaturated amino alcohols and ethers. Cis- and trans-1,4-dimethoxybut-2-ene-derived aziridines were prepared, and their
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