543039
(R)-1,4-Dioxaspiro[4.5]decane-2-carboxaldehyde
Synonym(s):
(R)-2,3-Cyclohexylideneglyceraldehyde, (R)-Cyclohexylideneglyceraldehyde, 2,3-O-Cyclohexylidene-D-glyceraldehyde, O,O-Cyclohexylidene-(R)-glyceraldehyde
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About This Item
InChI
1S/C9H14O3/c10-6-8-7-11-9(12-8)4-2-1-3-5-9/h6,8H,1-5,7H2/t8-/m0/s1
SMILES string
O=C[C@H]1COC2(CCCCC2)O1
InChI key
FFGZPNNLXMQFMO-QMMMGPOBSA-N
optical activity
[α]/D 60±10° in chloroform
refractive index
n20/D 1.472 (lit.)
density
1.108 g/mL at 25 °C (lit.)
functional group
aldehyde, ether, ketal
Quality Level
Application
- Proline-catalyzed Diels Alder reaction
- Stereodivergent synthesis of carbahexofuranoses employing a Wittig olefination-Claisen rearrangement protocol
- Wittig reactions
- Crotylation reactions
- Asymmetric synthesis of Goniothalesdiol A via stereocontrolled allylation and base-catalyzed oxy-Michael addition
Other Notes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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