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Merck
CN

560871

2-Methyl-2-propanesulfinamide

97%, racemic

Synonym(s):

(±)-tert-Butylsulfinamide, 1,1-Dimethylethylsulfinamide, 2-Methyl-2-propanesulfinamide, 2-Methylpropan-2-sulfinamide, tert-Butanesulfinamide, tert-Butylsulfinamide

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About This Item

Linear Formula:
(CH3)3CS(O)NH2
CAS Number:
Molecular Weight:
121.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Product Name

2-Methyl-2-propanesulfinamide, 97%, racemic

InChI key

CESUXLKAADQNTB-UHFFFAOYSA-N

SMILES string

CC(C)(C)S(N)=O

InChI

1S/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3

assay

97%

form

solid

mp

97-101 °C (lit.)

storage temp.

2-8°C

Quality Level

Application

Synthesis of 4-sulfonyliminopiperidine and its reaction with benzyl Grignard to form an important pharmaceutical building block, 4-benzyl-4-aminopiperidne. Also used to prepare spiro tosylaziridines via methylene insertion into the derived sulfonylimine.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Synlett, 2565-2565 (2006)
Synlett, 833-833 (2006)

Articles

Ellman's sulfinamide is available in both enantiomeric and racemic forms for your research. This versatile and useful auxiliary has found extensive use both in academics and industry.

Related Content

Ellman group developed electron-rich phosphine ligands for C-H functionalization and tert-Butanesulfinamide for asymmetric amine synthesis.

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