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Sigma-Aldrich

Poly(sodium 4-styrenesulfonate) solution

average Mw ~200,000, 30 wt. % in H2O

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Synonym(s):
PSS, Poly(4-styrenesulfonic acid) sodium salt
Linear Formula:
(C8H7NaO3S)n
CAS Number:
25704-18-1
MDL number:
MFCD00084449
NACRES:
NA.23

mol wt

average Mw ~200,000

concentration

30 wt. % in H2O

refractive index

n20/D ~1.3961

pH

~6.4

viscosity

~118 cP

density

1.1471 g/mL at 25 °C

InChI

1S/C8H8O3S/c1-2-7-3-5-8(6-4-7)12(9,10)11/h2-6H,1H2,(H,9,10,11)

InChI key

MAGFQRLKWCCTQJ-UHFFFAOYSA-N

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General description

Poly (Sodium 4-Styrenesulfonate) (PSS), a strong anionic polyelectrolyte, possesses a number of negative charges along its backbone chain. The ionic charges, in such electrolytes, are largely independent of the pH condition. PSS deposition exhibits layer by layer assembly. Alternate adsorption of polycations and polyanions by electrostatic attraction forms polyelectrolyte multilayers (PEMs). PSS-graphite oxide shows high performance of electric double layer capacitance compared to pristine graphite oxide on account of the layer by layer assembly. PSS coating on nanoparticles inhibit formation of agglomeration.

Features and Benefits

Anionic polyelectrolyte

Storage Class Code

12 - Non Combustible Liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Yu-Fen Huang et al.
Langmuir : the ACS journal of surfaces and colloids, 23(25), 12777-12781 (2007-11-02)
In this article, we report a simple approach for selectively sensing Fe2+ ions using CTAB-stabilized Au-Ag nanorods (CTAB-Au-Ag NRs) in the presence of poly(sodium 4-styrenesulfonate) (PSS). The prepared CTAB-Au-Ag NRs exhibit an intense longitudinal surface plasmon resonance absorption (>10(9) M(-1)
Hae-Kyung Jeong et al.
ACS nano, 4(2), 1162-1166 (2010-01-27)
We propose a new material for high power and high density supercapacitors with excellent cycle stability. Graphite oxide (PSS-GO) intercalated with poly(sodium 4-styrensulfonate) showed high performance of electric double layer capacitance (EDLC) compared to that of the pristine graphite oxide.
Thidarat Angwarawong et al.
Dental materials journal, 30(2), 158-169 (2011-03-23)
Polyelectrolyte multilayer (PEM) film can modify the surface properties of materials to improve cellular responses. In this study poly(diallyldimethylammonium chloride) (PDADMAC), poly(sodium 4-styrene sulfonate) (PSS) and poly(4-styrenesulfonic acid-co-maleic acid) sodium salt (PSS-co-MA) were assembled into PEM {(PDADMAC/PSS)(4)/PDADMAC+PSS-co-MA} film on glass
Lulu Han et al.
Langmuir : the ACS journal of surfaces and colloids, 28(1), 193-199 (2011-11-29)
Poly(sodium 4-styrenesulfonate) (PSS)/poly(diallyldimethylammonium chloride) (PDADMAC) multilayers were treated with 1-5 M NaCl solutions, resulting in continuous changes in the physicochemical properties of the multilayers. Significant mass loss was observed when the salt concentration was higher than 2 M and reached
Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly (sodium 4-styrenesulfonate).
Stankovich S, et al
Journal of Materials Chemistry, 16(2), 155-158 (2006)
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Articles

Polyelectrolyte Multilayer Films and Membrane Functionalization

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

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