641588
Dodecyl methyl sulfoxide
98%
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About This Item
Empirical Formula (Hill Notation):
C13H28OS
CAS Number:
Molecular Weight:
232.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
221-369-6
MDL number:
Assay:
98%
Form:
solid
InChI key
CJPDBKNETSCHCH-UHFFFAOYSA-N
InChI
1S/C13H28OS/c1-3-4-5-6-7-8-9-10-11-12-13-15(2)14/h3-13H2,1-2H3
SMILES string
CCCCCCCCCCCCS(C)=O
assay
98%
form
solid
mp
59-63 °C (lit.)
functional group
sulfoxide
Quality Level
Related Categories
General description
Dodecyl methyl sulfoxide can be synthesized via oxidation of dodecyl methyl sulfide with sodium periodate.
Application
Dodecyl methyl sulfoxide can be used as a substitute for dimethyl sulfoxide in Swern oxidation of primary allylic and benzylic alcohols to the corresponding aldehydes and secondary alcohols to the corresponding ketones.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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"New odorless method for the Corey?Kim and Swern oxidations utilizing dodecyl methyl sulfide (Dod-S-Me)"
Ohsugi I-S, et al.
Tetrahedron, 59(42), 8393-8398 (2003)
"New odourless protocols for efficient Pauson?Khand annulations"
Brown.AJ, et al.
Organic & Biomolecular Chemistry, 3(13), 2396-2398 (2005)
"New non-volatile and odorless organosulfur compounds anchored on ionic liquids. Recyclable reagents for Swern oxidation"
He X and Chan HT
Tetrahedron, 62(14), 3389-3394 (2006)
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