648418
(−)-DIP-Chloride™ solution
50-65 wt. % in heptane
Synonym(s):
(−)-B-Chlorodiisopinocampheylborane, (−)-Chlorodiisopinocampheylborane, Chlorobis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane, Diisopinocampheylchloroborane
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About This Item
Product Name
(−)-DIP-Chloride™ solution, 50-65 wt. % in heptane
InChI
1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m1/s1
SMILES string
C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(Cl)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C
InChI key
PSEHHVRCDVOTID-VMAIWCPRSA-N
concentration
50-65 wt. % in heptane
density
0.895 g/mL at 25 °C
Quality Level
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Application
- Enantioselective reduction of α, β-unsaturated trifluoromethyl ketones into corresponding secondary allylic alcohols.
- Asymmetric reduction of aromatic and aliphatic α-halomethyl ketones to haloalcohols.
General description
Legal Information
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
<-22.0 °F - closed cup
flash_point_c
< -30 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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