Key Documents

675547

1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

Name: 1,2-Bis[(2<I>S</I>,5<I>S</I>)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate
Brand: ALDRICH

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About This Item

Empirical Formula (Hill Notation):

C₂₂H₄₀BF₄P₂Rh

CAS Number:

213343-65-8

Molecular Weight:

556.21

UNSPSC Code:

12352005

PubChem Substance ID:

24885287

NACRES:

NA.22

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Properties

form

solid

Quality Level

100

mp

152.2-156.3 °C

functional group

phosphine

SMILES string

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@H]2CC[C@H](C)P2CCP3[C@@H](C)CC[C@@H]3C

InChI

1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m0.../s1

InChI key

CVUPEPGZCZHSOF-ASDDUFFSSA-N

Description

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

Asymmetric hydrogenation

Legal Information

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number

MKBV9641V

14601KE

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Articles

DuPhos and BPE Ligands

Asymmetric hydrogenation enables scalable synthesis of single-enantiomer compounds with minimal byproducts, ideal for commercial manufacturing.

Global Trade Item Number

SKU	GTIN
675547-500MG	04061832624334
675547-100MG	04061832624327