690821
1,3-Dimethoxyimidazolium hexafluorophosphate
98%, complies for IR spectroscopy
Synonym(s):
(OMe)2Im-PF6
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About This Item
Empirical Formula (Hill Notation):
C5H9F6N2O2P
CAS Number:
Molecular Weight:
274.10
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥98% (13C-NMR), ≥98% (31P-NMR), 98%
Form:
solid
InChI
1S/C5H9N2O2.F6P/c1-8-6-3-4-7(5-6)9-2;1-7(2,3,4,5)6/h3-5H,1-2H3;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.COn1cc[n+](OC)c1
InChI key
KBRFXVGODOTNGL-UHFFFAOYSA-N
assay
≥98% (13C-NMR), ≥98% (31P-NMR), 98%
form
solid
mp
84 °C
suitability
complies for IR spectroscopy
Quality Level
Related Categories
Application
1,3-Dimethoxyimidazolium hexafluorophosphate can be used:
- As an ionic liquid and N-heterocyclic carbene (NHC) precatalyst.
- To prepare bis(1,3-dimethoxyimidazolin-2-ylidene)silver(I) hexafluoridophosphate complex, which acts as an N-heterocyclic carbene.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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N, N′-Di (alkyloxy) imidazolium salts: New patent-free ionic liquids and NHC precatalysts
Laus G, et al.
Zeitschrift fur Naturforschung B, 62(3), 295-308 (2007)
Crystal structure of bis (1, 3-dimethoxyimidazolin-2-ylidene) silver (I) hexafluoridophosphate, N-heterocyclic carbene (NHC) complex
Rietzler B, et al.
Acta Crystallographica Section E: Crystallographic Communications, 71(12), m251-m252 (2015)
N,N-Di(alkoxy)imidazolium salts: new patent-free ionic liquids and NHC-precatalysts
Laus, G., et al.
Zeitschrift fur Naturforschung, B: Chemical Sciences, 62, 295-308 (2007)
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