692204
(R)-[(RuCl(SEGPHOS®)2(μ-Cl)3[NH2Me2]
别名:
二甲基铵二氯三(μ-氯)二[(R)-(+)-5,5′-二(二苯基膦基)-4,4′-联-1,3-苯并二噁唑]二钌酸盐(II)
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关于此项目
线性分子式:
(CH3)2NH2+[C76H56Cl5O8P4Ru2]-
化学文摘社编号:
分子量:
1646.64
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
form
powder
Quality Segment
reaction suitability
reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation
functional group
amine, phosphine
storage temp.
2-8°C
SMILES string
Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.C3Oc4ccc(P(c5ccccc5)c6ccccc6)c(c4O3)-c7c8OCOc8ccc7P(c9ccccc9)c%10ccccc%10.C%11Oc%12ccc(P(c%13ccccc%13)c%14ccccc%14)c(c%12O%11)-c%15c%16OCOc%16ccc%15P(c%17ccccc%17)c%18ccccc%18
InChI
1S/2C38H28O4P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-3-2;;;;;;;/h2*1-24H,25-26H2;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1
InChI key
RENFEASRVBXAEN-UHFFFAOYSA-M
General description
(R)-[(RuCl(SEGPHOS®))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS®, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.
Legal Information
与 Takasago 合作销售，仅用于研究目的。日本注册号 3148136、3549390
SEGPHOS is a registered trademark of Takasago Intl. Corp.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable