716715
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine
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About This Item
Empirical Formula (Hill Notation):
C17H20NP
CAS Number:
Molecular Weight:
269.32
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C17H20NP/c1-3-9-16(10-4-1)19(14-15-8-7-13-18-15)17-11-5-2-6-12-17/h1-6,9-12,15,18H,7-8,13-14H2/t15-/m0/s1
SMILES string
C1CN[C@@H](C1)CP(c2ccccc2)c3ccccc3
InChI key
IWRBGJKCDORZHK-HNNXBMFYSA-N
form
liquid
optical activity
[α]22/D −24.0°, c = 0.5 in ethanol
refractive index
n20/D 1.614
density
1.043 g/mL at 25 °C
functional group
phosphine
Quality Level
Application
Catalytic ligand in:
- Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignans
- Preparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal
Legal Information
Sold under license from Kanata Chemical Technologies Inc. for research purposes only.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
Regulatory Information
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