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766054

P-Chlorodiphenylphosphine

99%, liquid

Synonym(s):

Diphenylphosphinous chloride

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About This Item

Linear Formula:
(C6H5)2PCl
CAS Number:
1079-66-9
Molecular Weight:
220.63
NACRES:
NA.22
PubChem Substance ID:
329767202
UNSPSC Code:
12352128
EC Number:
214-093-2
MDL number:
MFCD00000529
Beilstein/REAXYS Number:
512032
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Product Name

P-Chlorodiphenylphosphine, 99%

vapor density

7.8 (vs air)

Quality Level

100

assay

99%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.636 (lit.)

bp

320 °C (lit.)

density

1.194 g/mL at 25 °C, 1.229 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

ClP(c1ccccc1)c2ccccc2

InChI

1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

XGRJZXREYAXTGV-UHFFFAOYSA-N

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

280.4 °F

flash_point_c

138 °C

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP0510
SHBL1877
SHBL0052
SHBJ3098
SHBG9229V

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Jaewoo Kwak et al.
Dalton transactions (Cambridge, England : 2003), 44(10), 4765-4772 (2015-02-11)
A series of mono-, di-, and tri-phosphine oxide substituted triarylboranes, Mes2BAr (1), MesBAr2 (2), and BAr3 (3) (Ar = 4-(Ph2PO)-2,6-Me2-C6H2) were prepared to investigate the effect of a phosphine oxide group (Ph2PO) on Lewis acidity enhancement of triarylboranes. The X-ray

Global Trade Item Number

SKUGTIN
766054-25G04061832923451