Skip to Content
Merck
CN

Key Documents

View All Documentation

771406

Zinc trifluoromethanesulfinate

Synonym(s):

Baran trifluoromethylation reagent, 1,1,1-Trifluoro-methanesulfinic acid zinc salt (2:1), Bis(((trifluoromethyl)sulfinyl)oxy)zinc, TFMS

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C2F6O4S2Zn
CAS Number:
39971-65-8
Molecular Weight:
331.53
MDL number:
MFCD25978123
UNSPSC Code:
12352103
NACRES:
NA.22
Form:
solid
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

form

solid

Quality Level

100

reaction suitability

reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation

mp

151-157 °C

storage temp.

2-8°C

SMILES string

FC(F)(F)S(=O)O[Zn]OS(=O)C(F)(F)F

InChI

1S/2CHF3O2S.Zn/c2*2-1(3,4)7(5)6;/h2*(H,5,6);/q;;+2/p-2

InChI key

UANOWFITUWBPCF-UHFFFAOYSA-L

Application

Zinc trifluoromethanesulfinate (TFMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Other Notes

Frequently Asked Questions are available for this Product.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCP8736
MKCR0035
MKCM2661
MKCJ5620
MKCF4015

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Baran Diversinates™

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

Related Content

Baran Reagents FAQ

Baran Reagents - FAQ

Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified

Global Trade Item Number

SKUGTIN
771406-1G04061826646786
771406-10G04061833433188