795569
Garg 4,5-indolyne precursor
95%
别名:
4-(Trimethylsilyl)-1H-indol-5-yl trifluoromethanesulfonate
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关于此项目
经验公式（希尔记法）:
C12H14F3NO3SSi
化学文摘社编号:
分子量:
337.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
solid
Quality Segment
assay
95%
form
solid
mp
43-48 °C
functional group
fluoro, triflate
storage temp.
2-8°C
SMILES string
O=S(OC1=C([Si](C)(C)C)C2=C(NC=C2)C=C1)(C(F)(F)F)=O
InChI
1S/C12H14F3NO3SSi/c1-21(2,3)11-8-6-7-16-9(8)4-5-10(11)19-20(17,18)12(13,14)15/h4-7,16H,1-3H3
InChI key
LLCJFYYASDIOJN-UHFFFAOYSA-N
General description
Garg 4,5-indolyne precursor is an indolyne precursor developed by Professor Neil Garg and coworkers. It is widely used for the synthesis of various N-heterocyclic based compounds. It is also useful for the preparation of substituted indoles (Diels–Alder and azide cycloaddition products).
Application
Indolyne precursor can be activated under mild fluoride conditions, which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable