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805238

FK 102 Co(II) PF6 salt

Synonym(s):

Greatcell Solar®, tris(2-(1H-pyrazol-1-yl)pyridine)cobalt(II) di[hexafluorophosphate]

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About This Item

Empirical Formula (Hill Notation):
C24H21CoF12N9P2
CAS Number:
1392221-69-0
Molecular Weight:
784.35
NACRES:
NA.23
PubChem Substance ID:
329768922
UNSPSC Code:
12352103
MDL number:
MFCD29037024
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assay

98%

Quality Level

100

form

powder

mp

362 °C

SMILES string

F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.N1(C2=NC=CC=C2)N=CC=C1.C3(N4C=CC=N4)=CC=CC=N3.C5(N6C=CC=N6)=CC=CC=N5.[Co+2]

InChI

1S/3C8H7N3.Co.2F6P/c3*1-2-5-9-8(4-1)11-7-3-6-10-11;;2*1-7(2,3,4,5)6/h3*1-7H;;;/q;;;+2;2*-1

InChI key

MLELXRWOHQBFBO-UHFFFAOYSA-N

Application

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices.
FK102 cobalt complexes offer guaranteed performance, high reproducibility, consistent results, and are of highest purity. In comparison to triiodide-based redox electrolytes, cobalt complexes in general increase photovoltages and particularly at lower light levels (e.g. for indoor applications), significantly increase device power output.
Recommended use:
In liquid-based electrolytes: typically 0.15-0.2M of Co(II) and ca. 0.05M Co(II)
In solid-state photovoltaic cells: up to 10 weight % added to the hole transport material system.

Legal Information

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell SolarMaterials Pty Ltd.
Dyesol is a registered trademark of Greatcell Solar
Greatcell Solar is a registered trademark of Greatcell Solar

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW1704V

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Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films
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Global Trade Item Number

SKUGTIN
805238-5G04061832979922