901361
N-((Methylsulfonyl)oxy)acetimidoyl chloride
≥95%
Synonym(s):
(1-Chloroethylidene)azanyl ester methanesulfonic acid
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About This Item
Empirical Formula (Hill Notation):
C3H6ClNO3S
CAS Number:
Molecular Weight:
171.60
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
InChI key
MAVJMVPCGSHQGN-UHFFFAOYSA-N
InChI
1S/C3H6ClNO3S/c1-3(4)5-8-9(2,6)7/h5H,1H2,2H3
SMILES string
[S](=O)(=O)(ONC(=C)Cl)C
assay
≥95%
form
powder or crystals
functional group
amine, chloro, sulfonic acid
Quality Level
Application
This air- and moisture-stable reagent enables the direct functionalization of pyridines under mild conditions for late-stage diversification of complex and drug-like molecules.
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Patrick S Fier
Journal of the American Chemical Society, 139(28), 9499-9502 (2017-07-06)
Herein is reported the design and application of a reagent for the direct functionalization of pyridines. These reactions occur under mild conditions and exhibit broad functional group tolerance, enabling the late-stage functionalization of drug-like molecules. The reagent can be easily
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