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Merck
CN

915157

iPr-PDI

≥95%, powder

Synonym(s):

N,N-Bis(2,6-diisopropylphenyl)perylene-3,4,9,10-bis(dicarboximide)

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About This Item

Empirical Formula (Hill Notation):
C48H42N2O4
CAS Number:
82953-57-9
Molecular Weight:
710.86
MDL number:
MFCD28100818
UNSPSC Code:
12352101
NACRES:
NA.22

Key Documents

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Product Name

iPr-PDI, ≥95%

SMILES string

[n]2([c](c3c4c5c(c6c7c8c([c]([n]([c](c8cc6)=O)c9c(cccc9C(C)C)C(C)C)=O)ccc7c5cc3)ccc4[c]2=O)=O)c1c(cccc1C(C)C)C(C)C

InChI

1S/C48H42N2O4/c1-23(2)27-11-9-12-28(24(3)4)43(27)49-45(51)35-19-15-31-33-17-21-37-42-38(22-18-34(40(33)42)32-16-20-36(46(49)52)41(35)39(31)32)48(54)50(47(37)53)44-29(25(5)6)13-10-14-30(44)26(7)8/h9-26H,1-8H3

InChI key

NAZODJSYHDYJGP-UHFFFAOYSA-N

assay

≥95%

form

powder

mp

>300 °C

storage temp.

−20°C

Quality Level

100

Application

iPr-PDI is a perylene based organic photocatalyst with a variety of demonstrated uses, including the reduction of aryl halides and the iodoperfluoroalkylation of alkenes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Reduction of aryl halides by consecutive visible light-induced electron transfer processes

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Cristian Rosso et al.
Organic letters, 21(13), 5341-5345 (2019-06-30)
Two efficient continuous flow iodoperfluoroalkylation methods are described: using 0.05 mol % perylene diimide (PDI) photocatalyst under 450 nm irradiation or substoichiometric triethylamine under 405 nm irradiation. These methods enable dramatically elevated productivity versus batch processes. The triethylamine-mediated method is
Indrajit Ghosh et al.
Science (New York, N.Y.), 346(6210), 725-728 (2014-11-08)
Biological photosynthesis uses the energy of several visible light photons for the challenging oxidation of water, whereas chemical photocatalysis typically involves only single-photon excitation. Perylene bisimide is reduced by visible light photoinduced electron transfer (PET) to its stable and colored

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