919551
PAd2-DalPhos
≥95%, powder
Synonym(s):
1-((1,3,5,7-Tetramethyl-2,4,6-trioxa-8-phosphaadamantan-8-yl)-2-(1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantan-8-yl)benzene
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About This Item
Empirical Formula (Hill Notation):
C26H36O6P2
Molecular Weight:
506.51
UNSPSC Code:
12352001
NACRES:
NA.22
Product Name
PAd2-DalPhos, ≥95%
Quality Level
Assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand
mp
234-237 °C
functional group
phosphine
Related Categories
Application
PAd2-DalPhos is ligand developed in the Stradiotto lab that when combined with a Ni(II) source forms an air stable precatalyst for cross coupling of primary heteroarylamines and (hetero)aryl chlorides.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Jillian S K Clark et al.
Angewandte Chemie (International ed. in English), 58(19), 6391-6395 (2019-03-16)
Base-metal catalysts capable of enabling the assembly of heteroatom-dense molecules by cross-coupling of primary heteroarylamines and (hetero)aryl chlorides, while sought-after given the ubiquity of unsymmetrical di(hetero)arylamino fragments in pharmacophores, are unknown. Herein, we disclose the new "double cage" bisphosphine PAd2-DalPhos
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