922633
5-Methyl-2-(3-thienyl)pyridine
≥95%, powder
Synonym(s):
Chattopadhyay′s PYT Ligand
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About This Item
Empirical Formula (Hill Notation):
C10H9NS
CAS Number:
Molecular Weight:
175.25
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
Product Name
5-Methyl-2-(3-thienyl)pyridine, ≥95%
Quality Level
Assay
≥95%
form
powder
mp
45-47 °C
storage temp.
−20°C
SMILES string
[s]1cc(cc1)c2ncc(cc2)C
InChI
1S/C10H9NS/c1-8-2-3-10(11-6-8)9-4-5-12-7-9/h2-7H,1H3
InChI key
UXJGBSHKYRDOPU-UHFFFAOYSA-N
Application
5-Methyl-2-(3-thienyl)pyridine is a ligand for the Ir-catalyzed directed C(sp2)-H and C(sp3)-H borylation of a diverse set of aryl, heteroaryl, and alkyl substrates.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Md Emdadul Hoque et al.
Journal of the American Chemical Society, 143(13), 5022-5037 (2021-03-31)
Here we describe the discovery of a new class of C-H borylation catalysts and their use for regioselective C-H borylation of aromatic, heteroaromatic, and aliphatic systems. The new catalysts have Ir-C(thienyl) or Ir-C(furyl) anionic ligands instead of the diamine-type neutral
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