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Merck
CN

922803

Sigma-Aldrich

[Pt(IPr*)(DMS)Cl2]

powder

Synonym(s):

Platinum N,N′-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazolium dimethylsulfide dichloride

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About This Item

Empirical Formula (Hill Notation):
C71H62Cl2N2PtS
Molecular Weight:
1241.31
UNSPSC Code:
12141733
NACRES:
NA.22

Key Documents

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Product Name

[Pt(IPr*)(DMS)Cl2],

form

powder

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

248-255 °C (decomposition)

Related Categories

Application

[Pt(IPr*)(DMS)Cl2] is a platinum NHC catalsyst used for olefin hydrosilylation.

Other Notes

A general protocol for the synthesis of Pt-NHC (NHC = N-heterocyclic carbene) hydrosilylation catalysts

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Benon P Maliszewski et al.
Dalton transactions (Cambridge, England : 2003), 49(41), 14673-14679 (2020-10-17)
A general, user-friendly synthetic route to [Pt(NHC)(L)Cl2] and [Pt(NHC)(dvtms)] (L = DMS, Py; DMS = dimethyl sulfide, dvtms = divinyltetramethylsiloxane, Py = pyridine) complexes has been developed. The procedure is applicable to a wide range of ligands and enables facile

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