923443
PhMPhos
powder
Synonym(s):
1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
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About This Item
Empirical Formula (Hill Notation):
C42H48FeP2
Molecular Weight:
670.62
UNSPSC Code:
12352200
NACRES:
NA.21
Form:
powder
Product Name
PhMPhos,
form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
application(s)
homogeneous catalyst
functional group
phosphine
greener alternative category
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).
Learn more about MPhos ligands and catalysts
Learn more about MPhos ligands and catalysts
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 923443-100MG | 04065269045335 |
| 923443-500MG | 04065269045342 |