924172
Tris[(1,1,1,3,3,3-hexafluoropropan-2-yl)oxy]silane
Synonym(s):
HSi(OCH(CF3)2)3
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About This Item
Empirical Formula (Hill Notation):
C9H4F18O3Si
CAS Number:
Molecular Weight:
530.18
MDL number:
NACRES:
NA.22
UNSPSC Code:
12352101
Form:
liquid
Related Categories
Application
Tris[(1,1,1,3,3,3-hexafluoropropan-2-yl)oxy]silane is a silylating reagent used to silylate the C-terminus of unprotected amino acids and peptides, allowing for coupling with N-silylated amino acids and peptides to form discrete peptide bonds using a one-pot method.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Wataru Muramatsu et al.
Journal of the American Chemical Society, 143(18), 6792-6797 (2021-05-01)
A one-pot peptide bond-forming reaction has been developed using unprotected amino acids and peptides. Two different silylating reagents, HSi[OCH(CF3)2]3 and MTBSTFA, are instrumental for the successful implementation of this approach, being used for the activation and transient masking of unprotected
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