924253
Deoxazole-quat
≥95%, powder
别名:
5,7-Di-tert-butyl-3-(4-(trifluoromethyl)phenyl)benzo[d]oxazol-3-ium tetrafluoroborate
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关于此项目
经验公式（希尔记法）:
C22H25BF7NO
化学文摘社编号:
分子量:
463.24
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.21
产品名称
Deoxazole-quat, ≥95%
Quality Segment
assay
≥95%
form
powder
reaction suitability
reagent type: ligand
mp
230-234 °C
SMILES string
CC(C)(C)C1=CC([N+](C2=CC=C(C(F)(F)F)C=C2)=CO3)=C3C(C(C)(C)C)=C1.F[B-2](F)(F)F
Application
Deoxazole-quat is an N-heterocyclic carbene salt which activates tertiary free alcohols for a C-C cross coupling reaction with aryl halides. The MacMillan group developed a mild, robust, and selective metallaphotoredox-based cross-coupling platform for the deoxygenative coupling for free alcohols using Deoxazole-quat, a Ni catalyst, and [Ir(dtbbpy)(ppy)2]PF6.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable