926108
(S)-RUCY™-XylBINAP
Takasago, powder
Synonym(s):
RuCl[(S)-daipena][(S)-xylbinap]
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About This Item
Empirical Formula (Hill Notation):
C71H73ClN2O2P2Ru
CAS Number:
Molecular Weight:
1184.82
MDL number:
UNSPSC Code:
12352116
NACRES:
NA.22
Product Name
(S)-RUCY™-XylBINAP, Takasago
InChI key
VBDGCLWXZBVBHR-UCPQXOCLSA-M
SMILES string
[Ru+]c9c(ccc(c9)OC)C(N)([C@@H](N)C(C)C)c%10ccc(cc%10)OC.P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3.[Cl-]
form
powder
reaction suitability
reagent type: ligand
functional group
phosphine
Quality Level
Related Categories
Application
(S)-RUCY™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.
Legal Information
Product of Takasago.
For research and development purposes only. PCT/JP2010/072838
For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and
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