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Merck
CN

926760

PTABS

≥95%, powder

Synonym(s):

4-(1,3,5-Triaza-7-phosphaadamantan-1-ium-1-yl)butane-1-sulfonate, Kapdiphos

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About This Item

Empirical Formula (Hill Notation):
C10H20N3O3PS
CAS Number:
Molecular Weight:
293.32
MDL number:
UNSPSC Code:
12352128
NACRES:
NA.21
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Product Name

PTABS, ≥95%

SMILES string

O=[S-](CCCC[N@+]1(C2)C[N@@]3C[N@@](C[P@]2C3)C1)(=[O-])=O

assay

≥95%

form

powder

reaction suitability

reagent type: ligand

functional group

phosphine

Quality Level

Related Categories

Application

PTABS is a water soluble phosphine ligand for use in a variety of cross-coupling reactions including Heck, Suzuki, and Sonagashira cross-couplings.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Udaysinh Parmar et al.
The Journal of organic chemistry, 86(13), 8900-8925 (2021-06-23)
Buchwald-Hartwig amination of chloroheteroarenes has been a challenging synthetic process, with very few protocols promoting this important transformation at ambient temperature. The current report discusses about an efficient copper-based catalytic system (Cu/PTABS) for the amination of chloroheteroarenes at ambient temperature

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