- 927791
927791
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) ChemBeads
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![[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98%](/deepweb/content/dam/sigma-aldrich/structure2/054/mfcd08064219.eps/_jcr_content/renditions/mfcd08064219-medium.png)
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)](/deepweb/content/dam/sigma-aldrich/structure9/010/mfcd00015757.eps/_jcr_content/renditions/mfcd00015757-medium.png)
form
solid
Quality Level
composition
~ 5 wt.% loading of catalyst
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
SMILES string
Cl[Pd]Cl.CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C.CN(C)c2ccc(cc2)P(C(C)(C)C)C(C)(C)C
InChI
1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;/q;;;;+2/p-2
InChI key
DWOZNANUEDYIOF-UHFFFAOYSA-L
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This Item | 678740 | 29513 | 29524 |
|---|---|---|---|
| form solid | form solid | form - | form - |
| composition ~ 5 wt.% loading of catalyst | composition - | composition - | composition - |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
![(S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] ≥97%, optical purity ee: ≥99%](/deepweb/content/dam/sigma-aldrich/structure3/063/a______29513.eps/_jcr_content/renditions/a______29513-medium.png)
![(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%](/deepweb/content/dam/sigma-aldrich/structure1/067/a______29524.eps/_jcr_content/renditions/a______29524-medium.png)
Application
Palladium-catalyzed coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Other Notes
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 1B Inhalation
Storage Class Code
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Regulatory Information
Certificate of Analysis
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Certificate of Origin
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